Olefin hydrogenation with iron carbonyls as catalysts
نویسندگان
چکیده
منابع مشابه
Olefin Hydrogenation with Iron Carbonyls as Catalysts
O estudo de [Fe(CO)5], [Fe2(CO)9] e [Fe3(CO)12] como precursores catalíticos nas reações de hidrogenação do ciclohexeno e 1-hexeno foi efetuado. Um reator fotoquímico com fluxo de H2 e irradiação UV-vis foi usado no processo. Os espectros infravermelho das amostras mostraram a formação de [Fe(CO)4(olefina)] e [HFe(CO)3(π-alila)] como intermediários. A atividade mostrada do [Fe2(CO)9] na hidroge...
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 1997
ISSN: 0103-5053
DOI: 10.1590/s0103-50531997000300005